In the RNA world hypothesis, the origin of life happened with RNA, and then DNA and proteins came later to take over for most of what RNA did originally as more specialized and efficient molecules.As for the first RNA, again we don know but one hypothesis is similar to what you propose in your question. There was a nucleotide rich soup with some source of energy that caused the nucleotides to spontaneously form chains. Some of these chains happened to have the property that they were self replicating, and at that point evolution by natural selection kicks in.
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